By Alan R. Katritzky (Ed.)
(from preface)Volume forty three of Advances in Heterocyclic Chemistry consists of six chapters by way of a global set of authors. David Hewitt (Australia) presents us with the 1st to be had complete evaluate of heterocyclic 6-membered earrings containing phosphorus and nitrogen as heteroatoms: the azophosphorins.Chapters 2 and three, either authored by way of Wilhelm Flitsch (Federal Republic of Germany), deal, respectively, with the chemistry of the azaazulenes (not formerly coated due to the fact 1958) and of hydrogenated porphyrins, a category of accelerating significance in biochemical techniques. The reactivity of ring-nitrogen atoms in azines towards electrophiles is roofed via M. R. Grimmett (New Zealand) and B. R. T. Keene (England) in bankruptcy 4.The longest bankruptcy of this quantity, authored by means of Roger Gallo and Christian Roussel (France) and Ulf Berg (Sweden), supplies a accomplished account of the quantitative therapy of steric results in hcteroaromatic compounds—a topic that has been complicated considerably through those authors. ultimately, V. N. Charushin and O. N. Chupakhin (USSR) and H. С van der Plas (The Netherlands) overview reactions of azines with bifunctional nucleophiles.
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Additional resources for Advances in Heterocyclic Chemistry, Vol. 43
N. Nikonov, Izv. Akad. Nauk SSSR, Ser. Khim. (lo), 2417 (1980). M. Forster, E. Juan, E. Carkovic, and N. Irma, Contrib. Cient. Tecnol. (Univ. Tee. Esrado, Santiago) 10(1), 47 (1980) [ C A 94, 1314201. K. B. Yatsimirskii, M. I. Kabachnik, E. I. Sinyavskaya, T. Y. Medved, Y. M. Polikarpov, B. P. Shcherbakov, and L. V. Zagorovskaya, Zh. Neorg. Khim. 25(8), 2213 (1980). ] 80TL1449 80ZOB476 80ZOB2809 8 1DIS(B) I89 I 8 11ZV1539 8 1JOC5373 81M11 81PS147 8 1PS207 8 1 PS255 8 1 PS269 81TL229 81 USP212298 8 1ZOB1434 81ZOB I481 82BBR1467 82IC543 821ZV127 821ZV2723 82IZV2730 82JOC4637 82MI1 82PS105 82URP888498 82ZN(B)965 82ZOB789 82ZOB930 82ZOB I099 T H E CHEMISTRY OF AZAPHOSPHORINES 33 J.
5-Cyanomethyl-4-azaazulenium perchlorate (27b),resulting from protonation of the conjugate base 28 (73CB1993), was shown by 'H-NMR spectroscopy to be completely delocalized (78CB2407). 27a 27b 26 28a R=H R=CH2CN c L 0-' Substantial perturbations of the azaazulenium n-system are to be expected from hydroxy groups in protonated 4-azaazulenones. Salts 29 (R = H and Me) were obtained from 11 by protonation and reaction with Meerwein's salts, respectively (69JCS(C)1028). The benzo derivative (15)gave salt 30 upon protonation with dry HBr (68TL1935).
Luzikova, M. A. Kazankova, and V V. Christokletov, Zk. Obshch. Khim. 52(10), 2 172 (1 982). Y. G. Gololobov and L. I. Nesterova, Zh. Obshch. Khim. 52(1I), 2465 (1982). D. J. Collins, P. F. Drygala, and J. M. Swan, Ausi. J. Chem. 36,2095 (1983). M. Cygler and J. Skolimowski, Can. J. Chem. 61(3). 427 (1983). B. A. Arbuzov and E. N. Dianova, Izu. Akad. Nauk SSSR, Ser. Khim. (2),41 8 (1983). A M. Kibardin, T. K. Gazizov, K. M. Enikeev, and A. N. Pudovik’, Izu. Akad. Nuuk SSSR. Ser. Khim. (2), 432 (1983).
Advances in Heterocyclic Chemistry, Vol. 43 by Alan R. Katritzky (Ed.)